
AISI 422 (UNS S42200 / Type 422) is a hardenable, martensitic stainless steel engineered primarily for high-strength service at elevated operating temperatures.
While baseline martensitic grades like AISI 410 or 420 begin to lose their structural properties above 900°F (482°C), AISI 422 maintains excellent creep-rupture strength, high resistance to scaling, and structural integrity at continuous service temperatures up to 1200°F (649°C). This stability makes it a core material for high-stress components in steam turbines, aerospace systems, and power plants.
The elevated high-temperature performance of 422 stainless steel is achieved by introducing transition metal carbide-formers (tungsten, vanadium, and molybdenum) into a higher-carbon chromium matrix.
| Element | Minimum % | Maximum % | Metallurgical Purpose |
| Chromium (Cr) | 11.00% | 13.00% | Provides basic corrosion and high-temperature scaling resistance. |
| Carbon (C) | 0.20% | 0.25% | Increases martensitic hardness and strength potential during heat treat. |
| Molybdenum (Mo) | 0.75% | 1.25% | Restricts grain growth and boosts high-temperature creep strength. |
| Tungsten (W) | 0.75% | 1.25% | Forms stable carbides that resist softening and tempering at high heats. |
| Vanadium (V) | 0.15% | 0.30% | Refines grain structure and increases overall wear resistance. |
| Nickel (Ni) | 0.50% | 1.00% | Balances the microstructure, improving toughness post-quench. |
When sourced as a round bar or rod, Type 422 is typically delivered in the hardened and tempered condition (often conforming to ASTM A565 Grade 616).
Tensile Strength: $\ge 140,000 \text{ psi}$ ($965 \text{ MPa}$)
Yield Strength (0.2% Offset): $\ge 110,000 \text{ psi}$ ($760 \text{ MPa}$)
Elongation (in 2"): $\ge 15\%$
Typical Hardness Range: 290 to 350 HBW (31 to 38 HRC)
To develop its target mechanical properties, Type 422 undergoes a strict thermal profile:
Austenitizing: Heated to $1900^\circ\text{F} - 1950^\circ\text{F}$ ($1038^\circ\text{C} - 1066^\circ\text{C}$) followed by an oil or air quench to form a fully martensitic matrix.
Tempering: Must be tempered at a minimum of $1100^\circ\text{F}$ ($593^\circ\text{C}$) to guarantee high-temperature stability. Because of secondary hardening effects driven by the tungsten and vanadium additions, tempering at these high ranges precipitates a fine dispersion of spheroidized carbides (as visualized above) which locks the matrix against high-temperature creep.
Machining: Rated at approximately 40-45% of AISI 1212. Because it is highly alloyed, it produces tough, stringy chips and exhibits rapid work hardening. Rigid setups, heavy sulfurized cutting oils, and sharp carbide tooling are mandatory.
Welding: Due to high carbon and alloy levels, Type 422 is highly prone to cold cracking. It requires strict preheating to $400^\circ\text{F} - 600^\circ\text{F}$ ($204^\circ\text{C} - 316^\circ\text{C}$), constant interpass control, and a mandatory immediate post-weld heat treatment (PWHT) / stress relief to temper the brittle heat-affected zone (HAZ).
If you are drafting purchase orders or validating mill test reports (MTRs) for 422 bars or rods, the material usually aligns with the following industrial baselines:
| Specifying Body | Standard Designation | Product Form Context |
| ASTM | ASTM A565 / A565M | Standard Specification for Martensitic Stainless Steel Bars for High-Temperature Service (Grade 616). |
| SAE / AMS | AMS 5655 | Aerospace Material Specification for bars, forgings, and mechanical tubing. |
| ASME | ASME SA565 | Boiler & Pressure Vessel Code equivalent baseline. |
| UNS | S42200 | Unified Numbering System metallurgical designation. |
Because of its unique blend of high thermal strength and corrosion resistance, AISI 422 bars are frequently machined into:
Steam Turbine Components: High-pressure bucket blades, rotors, and shroud bolting.
Aerospace Hardware: Valve components, structural aircraft fasteners, and gas turbine compressor wheels.
Power Generation Equipment: High-temperature structural pins, boiler trim parts, and heavy-duty reaction vessels.
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