
AISI 444 (UNS S44400) is a low-carbon, low-nitrogen, ferritic stainless steel stabilized with molybdenum, titanium, and/or niobium. It is often referred to as the "ferritic equivalent" to Grade 316, offering similar corrosion resistance without the high nickel content, making it more price-stable.
Because it is a dual-stabilized ferritic steel, it is exceptionally resistant to Stress Corrosion Cracking (SCC), a common failure point for austenitic steels like 304 and 316.
AISI 444 is widely recognized for its high molybdenum content ($2\%$), which provides superior pitting resistance.
| Standard | Designation |
| ASTM / AISI / SAE | 444 |
| UNS | S44400 |
| European (EN) | 1.4521 (X2CrMoTi18-2) |
| Japanese (JIS) | SUS 444 |
| Chinese (GB) | 00Cr18Mo2Ti |
The addition of Molybdenum and Titanium/Niobium is critical for its performance in aggressive environments.
Chromium (Cr): 17.5% â 19.5%
Molybdenum (Mo): 1.75% â 2.50%
Carbon (C): $\le$ 0.025%
Nitrogen (N): $\le$ 0.035%
Stabilizers (Ti + Nb): $0.20\% + 4 \times (C+N) \min$
Unlike the 420 series, Grade 444 cannot be hardened by heat treatment. It is typically supplied in the annealed condition.
| Property | Value |
| Tensile Strength ($R_m$) | $\ge$ 415 MPa |
| 0.2% Yield Stress ($R_{p0.2}$) | $\ge$ 275 MPa |
| Elongation ($A$ in 50mm) | $\ge$ 20% |
| Hardness (Rockwell B) | $\le$ 90 HRB |
Resistance to SCC: Being ferritic, AISI 444 is virtually immune to chloride-induced stress corrosion cracking, making it a superior choice over Grade 316 in hot water applications.
Pitting Resistance: The PREN (Pitting Resistance Equivalent Number) of AISI 444 is approximately 23â25, which is comparable to Grade 316.
Thermal Expansion: It has a lower coefficient of thermal expansion than austenitic steels, which reduces thermal fatigue in applications involving temperature cycling.
Magnetic: Like all ferritic steels, AISI 444 is ferromagnetic.
AISI 444 round bars and rods are frequently used in environments where chloride levels or temperature fluctuations are high:
Hot Water Tanks & Heat Exchangers: Due to its immunity to SCC and excellent thermal conductivity.
Solar Collectors: Used for framing and fluid handling where long-term durability is required.
Food Processing Equipment: Particularly for components exposed to salty or acidic food products (e.g., vinegar or brine).
Automotive Exhaust Systems: Specifically for components that require high-temperature oxidation resistance.
Water Treatment Facilities: For shafts and fittings in desalination or waste-water management.
Welding: AISI 444 is weldable using standard techniques, provided the carbon and nitrogen pickup is minimized. Using Grade 316L or 444 filler metal is common. The titanium/niobium stabilization prevents sensitization and intergranular corrosion in the heat-affected zone (HAZ).
Machinability: It machines similarly to Grade 316 but with less work-hardening. Rigid setups and sharp tools are recommended to manage the "gummy" nature typical of high-chromium ferritics.
Bending/Forming: It has good ductility but a higher yield-to-tensile ratio than 304, meaning it requires slightly more power to deform and exhibits more spring-back.
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